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                                       Details van artikel 197 van 243 gevonden artikelen
 
 
  Some Further Studies in Combustion Synthesis of the YBa2Cu307-x Superconductor
 
 
Titel: Some Further Studies in Combustion Synthesis of the YBa2Cu307-x Superconductor
Auteur: Lebrat, Jean-Pascal
Varma, Arvind
Verschenen in: Combustion science and technology
Paginering: Jaargang 88 (1993) nr. 3-4 pagina's 177-185
Jaar: 1993-02-01
Inhoud: The combustion synthesis of the YBa2Cu3Oz-x ceramic superconductor was achieved from CuBaO2 and Y2O3 mixtures, using both self-propagating high-temperature synthesis (SHS) and thermal explosion modes. Particular attention was paid to establishing the mechanism of formation of the YBa2Cu3O3-2 product. Previous studies included effects of BaO2 and Cu particle sizes, along with quenching of reacting pellets. It was shown that the mixture of reactants undergoes a complex sequence of reactions before eventually forming the final product. In the present work, the effect of the Y2O3 particle size has been investigated. The initiation of YBa2Cu3O7-x formation has also been studied by providing a portion of the copper as either Cu2O or CuO. It is shown that the oxidation of Cu to form Cu2O is a necessary step for the reaction to become self-sustaining, but that excessive oxidation to Cu2O inhibits the reaction, leading to partially reacted pellets.
Uitgever: Taylor & Francis
Bronbestand: Elektronische Wetenschappelijke Tijdschriften
 
 

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