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Details van artikel 194 van 243 gevonden artikelen
| Titel: |
Single Pulse Shock Tube Study of the Reaction Between Nitrogen Dioxide (NO2) and Carbon Monoxide (CO) |
| Auteur: |
Milks, D. Adams, T. N. Matula, R. A. |
| Verschenen in: |
Combustion science and technology |
| Paginering: | Jaargang 19 (1979) nr. 3-4 pagina's 151-159 |
| Jaar: |
1979-02-01 |
| Inhoud: |
The reaction between NO2 and CO has been studied in a single pulse shock tube in the temperature range 950-1500 °K and at a total concentration of approximately 2.5× 10-5 moles/cc. Both the measured ratios of ([CO2]/[CO])1 and ([NO]/[NO2])1 have been used in separate series of experiments to examine the reaction [image omitted] The Arrhenius frequency factor and activation energy for ka were found to be 1013.51±0.25 cc/mole-sec and 32000± 1300 cal/mole, respectively. This result for k12 is compared to literature values and the favorable comparison is taken as an indication that the modified single pulse shock tube analysis employed in this study leads to more reliable chemical kinetic data. The analysis methods include a special test mixture filling technique and a relative concentration at time solution for determining the final species concentration. These techniques reduce variation in the shocked gas reaction time and avoid concentration measurement errors associated with volume expansion sampling in a shock tube. |
| Uitgever: |
Taylor & Francis |
| Bronbestand: |
Elektronische Wetenschappelijke Tijdschriften |
Details van artikel 194 van 243 gevonden artikelen
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