|
| << vorige | volgende >> |
Tijdschrift beschrijving
Alle jaargangen van het bijbehorende tijdschrift
Alle afleveringen van het bijbehorende jaargang
Alle artikelen van de bijbehorende aflevering
Details van artikel 21 van 26 gevonden artikelen
| Titel: |
SELECTIVE CATALYTIC REDUCTION OF NITRIC OXIDE BY AMMONIA ON PILLARED CLAY CATALYSTS: POSSIBLE MECHANISM AND PROMOTERS |
| Auteur: |
Chen, J. P. Yang, R. T. |
| Verschenen in: |
Chemical engineering communications |
| Paginering: | Jaargang 152 (1996) nr. 1 pagina's 161-171 |
| Jaar: |
1996-10-01 |
| Inhoud: |
The delaminated Fe203-pillared clay shows high activities for selective catalytic reduction (SCR) of NO by NH2. Temperature program desorption (TPD) studies show that large amounts of NO., are adsorbed on the pillared clay catalyst at the SCR reaction temperatures (i.e. near 400°C). This result indicates that a Langmuir-Hinshelwood type mechanism (for reaction between chemisorbed NO, and NH, on the surface to form N2) is operative for the pillared clay catalyst, which is in contrast to the SCR reaction on the commercial vanadia-based catalysts. The SCR activities for the delaminated Fe203-pillared clay catalyst are higher than that of a commercial-type V2O5 + WO3/TiO2 catalyst under SO2 + H20 free conditions, but became lower in the presence of SO2 +l H20. However, when promoted by doping 1-3% Cr203, the pillared clay catalyst exhibits higher SCR activities than the commercial-type catalyst in the presence of S02 + H2O at all practical SCR reaction temperatures |
| Uitgever: |
Taylor & Francis |
| Bronbestand: |
Elektronische Wetenschappelijke Tijdschriften |
Details van artikel 21 van 26 gevonden artikelen
| << vorige | volgende >> |