CONTINUUM MECHANICS APPLIED TO A VERY THIN LIQUID FILM: ESTIMATION OF SURFACE TENSION FOR THE n-ALKANES
Titel:
CONTINUUM MECHANICS APPLIED TO A VERY THIN LIQUID FILM: ESTIMATION OF SURFACE TENSION FOR THE n-ALKANES
Auteur:
Kim, Myung Jun Li, Dongming Slattery, John C.
Verschenen in:
Chemical engineering communications
Paginering:
Jaargang 118 (1992) nr. 1 pagina's 75-87
Jaar:
1992-11-01
Inhoud:
This analysis demonstrates that, at least in some cases, continuum mechanics can be successfully applied in problems involving very thin films, so long as proper recognition is given to long-range intermolecular forces and to the finite size of molecules. In this particular case, the integral mechanical energy balance is used to analyze a simple thought experiment in which a thin liquid film is slowly stretched. The result is an expression for surface tension as a function of the Hamaker constant describing liquid-liquid, long-range intermolecular forces, the molecular weight, and the liquid density, which is in good agreement with previous experimental measurements for n-alkanes.