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| Titel: |
RATE OF PHOTOCHLORINATION OF LIQUID n-HEPTANE |
| Auteur: |
Santarelli, Francesco Smith, J. M. |
| Verschenen in: |
Chemical engineering communications |
| Paginering: | Jaargang 1 (1974) nr. 6 pagina's 297-302 |
| Jaar: |
1974 |
| Inhoud: |
The rates of photochlorination of liquid solutions of Cl2 and n-heptane were measured at 25°C in a tubular-flow reactor. By using educed light intensities and short illuminated reactor lengths it was possible to obtain low conversions of chlorine (approach differential-reactor operation) for this fast reaction. The rate of morochloride production was first order in chlorine concentration and first order in light intensity. An overall quantum yield of 0.8 × 108 g mole/Einstein was obtained At the low chlorine concentrations (> 1.5 mole 7percnt;) employed no dichlorides were found in the product. The monochlorides contained a little more of the primary isomer than has been observed in other photochemical studies. |
| Uitgever: |
Taylor & Francis |
| Bronbestand: |
Elektronische Wetenschappelijke Tijdschriften |
Details van artikel 5 van 5 gevonden artikelen
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