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  A Variable Supersaturation Condensation Particle Sizer
 
 
Titel: A Variable Supersaturation Condensation Particle Sizer
Auteur: Gallar, Carlos
Brock, Charles A.
Jimenez, Jose L.
Simons, Craig
Verschenen in: Aerosol science and technology
Paginering: Jaargang 40 (2006) nr. 6 pagina's 431-436
Jaar: 2006-07-01
Inhoud: A prototype variable supersaturation condensation particle sizer (VSCoPS) capable of measuring particle size distributions from 5 to 30 nm has been developed. This system design is adapted from existing condensation particle counter (CPC) technology with three significant differences: (1) the working fluid is a perfluorinated organic compound that is nonreactive toward, and not an effective solvent for, most laboratory or ambient particle compositions; (2) the vapor pressure of the working fluid is controlled by dilution of saturated air with vapor-free air at the same temperature; and (3) the optical block and condenser are located below the saturator, so that fluid condensed on the condenser walls does not flow back toward the saturator. By using fast-response flow controllers to vary the ratio of saturator and dilution air while keeping total flows and temperatures constant, the vapor saturation ratio in the condenser can be controlled with time constants of ∼ 1 s. The nucleation threshold diameter is changed by stepping through small increments in saturation ratio. The particle size distribution can be recovered by inverting the measured concentration using the known instrument response for each saturation ratio. Further development of the system may allow size distribution measurements to smaller particle diameters and scan times of <30 s at total particle concentrations as low as ∼ 100 cm-3.
Uitgever: Taylor & Francis
Bronbestand: Elektronische Wetenschappelijke Tijdschriften
 
 

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