Measurement of Both Nonvolatile and Semi-Volatile Fractions of Fine Particulate Matter in Fresno, CA
Titel:
Measurement of Both Nonvolatile and Semi-Volatile Fractions of Fine Particulate Matter in Fresno, CA
Auteur:
Grover, Brett D. Eatough, Norman L. Eatough, Delbert J. Chow, Judith C. Watson, John G. Ambs, Jeffrey L. Meyer, Michael B. Hopke, Philip K. Al-Horr, Rida Later, Douglas W. Wilson, William E.
Verschenen in:
Aerosol science and technology
Paginering:
Jaargang 40 (2006) nr. 10 pagina's 811-826
Jaar:
2006-10-01
Inhoud:
An intensive sampling campaign was performed in Fresno, CA during December 2003 measuring fine particulate matter including both the semi-volatile and nonvolatile fractions of the aerosol. Both the newly developed R&P FDMS Monitor and a PC-BOSS have been shown to measure total PM2.5 concentrations including semi-volatile nitrate and organic material. Good agreement was observed between the PC-BOSS and the R&P FDMS Monitor in this study with linear regression analysis resulting in a zero-intercept slope of 1.00 ± 0.02 and an R2 = 0.93. Several real-time measuring systems including the R&P Differential TEOM, the Met One BAMS, and a GRIMM Monitor were also employed and comparisons of total PM2.5 mass were made with the R&P FDMS Monitor. Agreement among these various monitors was generally good. However, differences were sometimes seen. Reasons for observed differences in the real-time mass measurement systems are explained by the composition and complexity of the measured aerosol, most importantly the composition of semi-volatile material. A newly automated ion chromatographic system developed by Dionex was also field tested and compared to both R&P 8400N Nitrate and integrated PC-BOSS inorganic species measurements. Sulfate and nitrate determined by the Dionex and PC-BOSS systems agreed. However, nitrate measured by the 8400N was low during fog events compared to the other two systems.