Field and Laboratory Evaluation of the Thermo Electron 5020 Sulfate Particulate Analyzer
Titel:
Field and Laboratory Evaluation of the Thermo Electron 5020 Sulfate Particulate Analyzer
Auteur:
Schwab, James J. Hogrefe, Olga Demerjian, Kenneth L. Dutkiewicz, Vincent A. Husain, Liaquat Rattigan, Oliver V. Felton, Henry D.
Verschenen in:
Aerosol science and technology
Paginering:
Jaargang 40 (2006) nr. 10 pagina's 744-752
Jaar:
2006-10-01
Inhoud:
The Thermo Electron Model 5020 Sulfate Particulate Analyzer is a recently commercialized instrument that provides continuous measurements of the sulfate component of ambient particulate matter. The technique uses a stainless steel rod placed inside a quartz oven to reduce the particle sulfate to sulfur dioxide; followed by pulsed fluorescence detection of the sulfur dioxide. Field and laboratory evaluations of a pre-production version of the analyzer are described as well as laboratory evaluations of the pre-production version and two production units. Laboratory tests concentrated on challenging the instruments with ammonium sulfate aerosol, but tests with sodium, potassium, and calcium sulfate are reported as well. The instrument performed very well in field and laboratory settings, reporting values that were highly correlated with continuous mass measurements in the lab, and 24-hour filters in the field. Conversion/detection efficiencies for ammonium sulfate in the laboratory, and for ambient sulfate aerosol at our rural site in Addison, New York, were both very close to 80%. Laboratory conversion efficiencies for calcium, sodium, and potassium sulfate salts ranged from 4% to 63%. These lower efficiencies for mineral-type sulfates will be an important consideration in areas with significant concentrations of sea salt or mineral dust sulfate, and less important for the high sulfate Eastern US which is dominated by ammonium sulfate.