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  Modeling Small Cluster Deposition on the Primary Particles of Aerosol Agglomerates
 
 
Titel: Modeling Small Cluster Deposition on the Primary Particles of Aerosol Agglomerates
Auteur: Rogak, Steven N.
Verschenen in: Aerosol science and technology
Paginering: Jaargang 26 (1997) nr. 2 pagina's 127-140
Jaar: 1997
Inhoud: Dense particles, such as the primary particles in aerosol agglomerates, are formed by coagulation with rapid coalescence, or by condensation-like growth. This latter mechanism is explored in a new model. It uses the discrete-sectional model to describe the evolution of the particle mass distribution. In addition, new equations are used to describe the formation of primary particles. Primary particles are “born” when a new particle is formed above a critical size Dmelt. Particles smaller than Dmelt are assumed to be liquid-like, sintering rapidly in the available time. Changes in the final primary particle size Dp can be attributed to growth from small particle deposition. This growth increases as the monomer source rate decreases. For conditions representative of TiO2 formation from chloride in a tube reactor, Dp/Dmelt ranges from 1.5 to 3. When Dmeit decreases, as would be expected if temperature decreases, Dp/Dmelt increases. The result is that Dp is much less sensitive to temperature than would be expected from simple sintering models.
Uitgever: Taylor & Francis
Bronbestand: Elektronische Wetenschappelijke Tijdschriften
 
 

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