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  Theoretical Study of Equilibrium Bipolar Charge Distribution on Nonuniform Primary Straight Chain Aggregate Aerosols
 
 
Titel: Theoretical Study of Equilibrium Bipolar Charge Distribution on Nonuniform Primary Straight Chain Aggregate Aerosols
Auteur: Yeh, Hsu-Chi
Cheng, Yung-Sung
Verschenen in: Aerosol science and technology
Paginering: Jaargang 2 (1982) nr. 3 pagina's 383-388
Jaar: 1982-11-29
Inhoud: A general theory describing the equilibrium bipolar charge distribution for straight chain aggregate aerosols consisting of primary spheres of different diameters was derived from a theory previously developed for linear chain aggregate of uniform spheres. The present theory is based on the assumptions that (1) the individual primary particles of a straight chain aggregate are charged independently, (2) the probability that a particular primary particle has acquired q elementary charges is governed by the Gaussian distribution predicted by Boltzmann's law, based on particle size; and (3) the resultant charge of a straight chain aggregate is the algebraic sum of the charges carried by the constituent primary spheres. The present theory can be stated as follows: The equilibrium bipolar charge distribution of straight chain aggregate aerosols with nonuniform primary spheres can be expressed by Boltzmann's law with an equivalent diameter such that deL = Σni=1 di. The limitations imposed by the assumptions are also discussed.
Uitgever: Taylor & Francis
Bronbestand: Elektronische Wetenschappelijke Tijdschriften
 
 

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