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  Determination of the Condensation Accommodation Coefficient of Sulfuric Acid on Water-Sulfuric Acid Aerosol
 
 
Titel: Determination of the Condensation Accommodation Coefficient of Sulfuric Acid on Water-Sulfuric Acid Aerosol
Auteur: Van Dingenen, Rita
Raes, Frank
Verschenen in: Aerosol science and technology
Paginering: Jaargang 15 (1991) nr. 2 pagina's 93-106
Jaar: 1991
Inhoud: Growth of water-sulfuric acid (H2O-H2SO4) aerosol resulting from condensation was studied as an isolated process in a batch reactor. Simultaneous measurement of aerosol distribution changes and the H2SO4 formation rate allowed the determination of the accommodation coefficient of H2SO4 on H2O- H2SO4 particles. For particles within a size range between 0.05 and 0.5 μm, and for a relative humidity of 50%, the accommodation coefficient was found to be between 0.02 and 0.09 (90% confidence limits). The Fuchs-Sutugin interpolation formula was adopted for describing the condensation process. The Sitarski-Nowakowski formula gave the same result within the particle size-range under study. Computer simulations of the aerosol distribution evolution during condensational growth, making use of a value for α within the experimental range, were performed as an independent test and showed excellent agreement with the experimental data.
Uitgever: Taylor & Francis
Bronbestand: Elektronische Wetenschappelijke Tijdschriften
 
 

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