Metallaborane reaction chemistry. Macropolyhedral metallaheteroborane synthesis by direct heteroatom insertion. Formation of the twenty-vertex [(η 5-C5Me5)IrB18H19S]− anion from nineteen-vertex syn-[(η 5-C5Me5)IrB18H20] 1 IUPAC nomenclatures for the two title compounds would be 9-pentahapto-pentamethylcyclopentadienyl-nido(type 7)-9-iridadodecaborano-(7,8,12:6′,7′,2′)-nido-decaborane for compound 1 and 9-pentahapto-pentamethylcyclopentadienyl-nido(type 7)-9-iridadodecaborano-(7,12:6′,7′)-arachno-9′-thiadecaboranate(1−) for anion 2. 1
Titel:
Metallaborane reaction chemistry. Macropolyhedral metallaheteroborane synthesis by direct heteroatom insertion. Formation of the twenty-vertex [(η 5-C5Me5)IrB18H19S]− anion from nineteen-vertex syn-[(η 5-C5Me5)IrB18H20] 1 IUPAC nomenclatures for the two title compounds would be 9-pentahapto-pentamethylcyclopentadienyl-nido(type 7)-9-iridadodecaborano-(7,8,12:6′,7′,2′)-nido-decaborane for compound 1 and 9-pentahapto-pentamethylcyclopentadienyl-nido(type 7)-9-iridadodecaborano-(7,12:6′,7′)-arachno-9′-thiadecaboranate(1−) for anion 2. 1
Auteur:
Shea, Suzanne L McGrath, Thomas D Jelı́nek, Tomáš Štı́br, Bohumil Thornton-Pett, Mark Kennedy, John D