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Details for article 2 of 7 found articles
| Title: |
Infrared spectrum of the CO-OCS van der Waals complex in the carbon monoxide stretching band |
| Author: |
XIA, CHANGHONG MCKELLAR, A.R. W. |
| Appeared in: |
Molecular physics |
| Paging: | Volume 98 (2000) nr. 20 pages 1669-1672 |
| Year: |
2000-10-20 |
| Contents: |
The rotation-vibration band of the weakly bound OCS-CO complex which corresponds to the carbon monoxide CO vibrational mode has been detected using a pulsed supersonic slit-jet expansion and a tunable infrared diode laser probe. The band was found to have a parallel (δKa = 0) structure, in good agreement with previous determinations of the structure of the complex. Its rotational structure appeared to be affected by numerous small (∼ 0.01 cm-1) perturbations in the upper state which probably are due to interactions with bound levels of a lower lying vibrational state of the complex. The band origin is located with a relatively small shift of + 1.23 cm-1 from that of the free CO molecule. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 2 of 7 found articles
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