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Details for article 1 of 17 found articles
| Title: |
A symmetry-based approach to the effective Hamiltonian for symmetric top molecules in degenerate vibronic states |
| Author: |
Liu, Xianming Miller, Terry A. |
| Appeared in: |
Molecular physics |
| Paging: | Volume 75 (1992) nr. 6 pages 1237-1258 |
| Year: |
1992-04-20 |
| Contents: |
The effective Hamiltonian for a symmetric top molecule in a degenerate vibronic state is obtained. Included in this Hamiltonian are the rotational, spin-rotational, spin-orbit coupling and electronic spin-spin interactions. The terms of the Hamiltonian are expressed as the product of molecular 'constants,' rotational angular momentum operators, and symmetry operators. A formalism is derived, and tables included, to determine whether or not a symmetry operator vanishes for a given vibronic state of a particular molecular symmetry. In this way, one can easily obtain all the non-vanishing Hamiltonian terms for a particular application. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 1 of 17 found articles
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