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Details for article 18 of 20 found articles
| Title: |
Simple parameter-dependent relations for the maximum value of the optical activity of push—pull molecules in solution |
| Author: |
SQUITIERI, EMILIO PAZ, J.L. HERNANDEZ, A.J. |
| Appeared in: |
Molecular physics |
| Paging: | Volume 101 (2003) nr. 14 pages 2279-2284 |
| Year: |
2003-07-20 |
| Contents: |
Based on the valence bond-charge transfer model for push-pull polyenes and reaction field theory, several parameter-dependent relations for selecting the molecule-solvent pair that produces a maximum value of the nonlinear optical response have been established. From these relations, we have determined a limit to the value of the dielectric constant of the solvent (above ε = 9) and effectiveness of the donor-acceptor pairs (between 5 and 6eV) beyond which the (hyper)polarizabilities of push-pull molecules in solution do not exhibit any significant change in magnitude. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 18 of 20 found articles
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