Bitumen-in-Water Emulsions: An Overview on Formation, Stability, and Rheological Properties
Title:
Bitumen-in-Water Emulsions: An Overview on Formation, Stability, and Rheological Properties
Author:
Gutierrez, Xiomara Silva, Felix Chirinos, Manuel Leiva, Javier Rivas, Hercilio
Appeared in:
Journal of dispersion science and technology
Paging:
Volume 23 (2002) nr. 1-3 pages 405-418
Year:
2002
Contents:
This paper describes the most relevant issues associated with the development of a technology; the formation of highly concentrated bitumen-in-water emulsions. Viscosity values for bitumen-in-water emulsions, containing between 70 and 85% (v/v) of bitumen, have been found to be several order of magnitude lower than the viscosity of the hydrocarbon itself. Thus, these emulsions, have potential applications in the processes of production, transportation, handling and commercialization of these extremely highly viscous hydrocarbons. The emulsions, the properties of which are discussed in this paper, were stabilized with mixtures of nonionic and natural surfactants (1,2) and formed using the HIPR (high internal phase ratio) technique (3). Information on the conditions required to produce emulsions with very narrow droplet diameter distributions is given. Results indicate that the mean droplet diameter, the droplet diameter distribution, and the bitumen volume fraction, significantly modify the rheological behavior. Emulsion stability was measured by following changes in the mean droplet diameter and in the rheological parameters with storage time.