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Details for article 7 of 8 found articles
| Title: |
Synthesis, spectroscopic characterization and x-ray studies of new complexes of organotin(IV) chlorides with N-alkylated 2-amino-1-cyclopentene-1-carbodithioic acids |
| Author: |
Tarassoli, Abbas Sedaghat, Tahereh Helm, Monte L. Norman, Arlan D. |
| Appeared in: |
Journal of coordination chemistry |
| Paging: | Volume 56 (2003) nr. 13 pages 1179-1189 |
| Year: |
2003-09-10 |
| Contents: |
The new complexes [Ph2SnCl(BuACDA)] (1), [Ph3Sn(BuACDA)] (2), [Bu2Sn(BuACDA)2] (3), [Ph2SnCl- (EtACDA)] (4), [Ph3Sn(EtACDA)] (5) and [Bu2Sn(EtACDA)2] (6) have been prepared from reactions between 2-N-butylamino-1-cyclopentene-1-carbodithioic acid (BuACDA) or 2-N-ethylamino-1-cyclopentene-1-carbodithioic acid (EtACDA) and Ph2SnCl2, Ph3SnCl or Bu2SnCl2. The 1H NMR, 119Sn NMR, UV-Vis and IR data and the elemental analyses support the structures of these organotin compounds. In all these complexes, the S-H proton has been removed and coordination takes place through the carbodithioate group. The 119Sn NMR data are consistent with the presence of five-coordinated tin(IV) in solution. Structures of 1 and 3 have also been confirmed by single crystal X-ray crystallography. The crystals of both are triclinic with space group . In the structure of 1, the tin environment is distorted trigonal bipyramidal with the Cl and one of the sulfur atoms in apical positions. In the structure of 3 the overall geometry at tin is highly distorted trans octahedral with the four S atoms on the equatorial plane. In both complexes, the ligand is asymmetrically chelated to the tin and there is an intramolecular hydrogen bond between the sulfur and the proton of the amine group. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 7 of 8 found articles
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