Nickel(II) di(pentyl)dithiocarbamates with P ligands
Titel:
Nickel(II) di(pentyl)dithiocarbamates with P ligands
Auteur:
Pastorek, Richard Kamenicek, Jiri Cvek, Boris Pavlicek, Marek Sindelar, Zdenek Zak, Zdirad
Verschenen in:
Journal of coordination chemistry
Paginering:
Jaargang 56 (2003) nr. 13 pagina's 1123-1129
Jaar:
2003-09-10
Inhoud:
Ni(II) di(pentyl)dithiocarbamates of composition [Ni(Pe2dtc)2], [NiX(Pe2dtc)(PPh3)] (X = Cl, Br, I, NCS), [Ni(NCS)(Pe2dtc)(PBut3)], [Ni(Pe2dtc)(PPh3)2]ClO4 and [Ni(Pe2dtc)(PPh3)2]PF6 (Pe2dtc = di(pentyl)dithio-carbamate, PPh3 = triphenylphosphine, PBut3 = tributylphosphine) have been synthesized. The complexes have been characterized by the usual methods. X-ray structure analyses confirmed the nature of [NiI(Pe2dtc)(PPh3)] and [Ni(Pe2dtc)(PPh3)2]ClO4 complexes.