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Details for article 1 of 116 found articles
| Title: |
ACETYL TRANSFER BETWEEN MANGANESE AND IRON COMPLEXES: REACTION OF ACETYLPENTACARBONYLMANGANESE WITH DICARBONYLCYCLOPENTADIENYLIRON(0) |
| Author: |
Wang, Ping Atwood, Jim D. |
| Appeared in: |
Journal of coordination chemistry |
| Paging: | Volume 30 (1993) nr. 3-4 pages 393-396 |
| Year: |
1993-12-01 |
| Contents: |
Reaction of Mn(CO)5(C(O)Me) with CpFe(CO)2- results in CpFe(CO)2Me, Cp2Fe2(CO)4 and Mn(CO)5- in less than five minutes at room temperature. Labeling the carbonyl of the acetyl puts the label only on a carbonyl of the CpFe(CO)2Me. Thus the acetyl is transferred from the manganese to the iron as a group, before CO dissociation leads to the methyl product. CO dissociation from CpFe(CO)2(C(O)Me) does not occur under the experimental conditions. A scheme is suggested to accommodate these observations. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 1 of 116 found articles
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