|
| << vorige | volgende >> |
Tijdschrift beschrijving
Alle jaargangen van het bijbehorende tijdschrift
Alle afleveringen van het bijbehorende jaargang
Alle artikelen van de bijbehorende aflevering
Details van artikel 8 van 23 gevonden artikelen
| Titel: |
Preparations, IR spectra and crystal structures of cyano-bridged bimetallic complexes of zinc(II) and cadmium(II) with tetracyanopalladate(II) |
| Auteur: |
Karadağ, Ahmet Bulut, Ahmet Senocak, Aysegul Ucar, Ibrahim Buyukgungor, Orhan |
| Verschenen in: |
Journal of coordination chemistry |
| Paginering: | Jaargang 60 (2007) nr. 19 pagina's 2035-2044 |
| Jaar: |
2007-10 |
| Inhoud: |
The novel heteronuclear compounds [Zn(hydet-en)2Pd(CN)4] (1) and [Cd(hydet-en)2Pd(CN)4] (2) {hydet-en: N-(2-hydroxyethyl-ethylenediamine)} have been synthesized and characterized by elemental analyses and IR spectra. The crystal structures of 1 and 2 have been determined by X-ray diffraction. Structural analysis shows that both compounds have shown a polymeric chain, in which the Zn(II)/Pd(II) and Cd(II)/Pd(II) centres are linked by two CN groups. Both zinc and cadmium atoms are six coordinate with two trans cyanide-nitrogen and four hydet-en N atoms in a distorted octahedron arrangement; the palladium atoms in 1 and 2 are four coordinate with four cyanide-C atoms in a square planar arrangement. The chains in both compounds are connected through weak interchain hydrogen bonds, N-H ··· O, N-H ··· N and O-H ··· N, thereby forming a three-dimensional network. |
| Uitgever: |
Taylor & Francis |
| Bronbestand: |
Elektronische Wetenschappelijke Tijdschriften |
Details van artikel 8 van 23 gevonden artikelen
| << vorige | volgende >> |