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Details for article 46 of 71 found articles
| Title: |
Synthesis and crystal structure of a Pt(II) complex with 3-amino-5-methyl-5-phenylhydantoin |
| Author: |
Bakalova, Adriana Petrova, Rosica Shivachev, Boris Varbanov, Hristo |
| Appeared in: |
Journal of coordination chemistry |
| Paging: | Volume 60 (2007) nr. 15 pages 1701-1707 |
| Year: |
2007-08 |
| Contents: |
The reaction of K2PtCl4 with 3-amino-5-methyl-5-phenylhydantoin (amphh, L) and KI in aqueous ethanol yields dark violet crystals of a binuclear platinum(II) complex. The molecular structure of the complex was determined by single-crystal X-ray diffraction methods. The complex crystallizes in the triclinic space group [image omitted] with a = 8.458(3), b = 11.016(2), c = 16.249(3) (Å), α = 94.630(14), β = 100.63(2), γ = 108.55(4)° and Z = 2. The structure consists of [K2L4]2+ cations and [Pt2I6]2- anions bridged by K-I bonds to form quasi-one-dimensional chains along the b axis. Chains are linked by K+ ··· π(Ph) interactions and N-H ··· O hydrogen bonds. The complex is compared with data for related structures. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 46 of 71 found articles
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