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Details for article 37 of 71 found articles
| Title: |
Syntheses, structures, and spectroscopic properties of copper(II) and cobalt(III) complexes containing 1,4,7-tribenzyl-1,4,7-triazacyclononane ligand |
| Author: |
Yang, Yong-Sheng Gu, Wen Qian, Jing Gao, Feng-Xian Yan, Shi-Ping |
| Appeared in: |
Journal of coordination chemistry |
| Paging: | Volume 60 (2007) nr. 15 pages 1681-1690 |
| Year: |
2007-08 |
| Contents: |
Three new complexes [CuL(N3)2] (1), [CuL(SCN)2] (2), and [CoL(SCN)3] (3) (L = 1,4,7-tribenzyl-1,4,7-triazacyclononane) have been synthesized and structurally characterized. Complex 1 crystallizes in monoclinic space group P2(1)/n with unit cell parameters a = 14.105(7), b = 8.999(5), c = 21.603(11) Å, β = 100.470(7)°. While 2 crystallizes in triclinic space group P-1 with unit cell parameters a = 9.6380(16), b = 10.6993(18), c = 15.798(3) Å, α = 106.636(3), γ = 116.478(3)°. Complex 3 crystallizes in trigonal space group P-3c1 with unit cell parameters a = 14.744(3), b = 14.744(3), c = 16.098(4) Å, γ = 120°. Elemental analysis, IR, UV-vis spectra of complexes 1-3 and ESR spectra of complexes 1-2 were also determined. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 37 of 71 found articles
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