The synthesis, characterization and spectral studies of Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) complexes with N,N-bis(2-{[(2-methyl-2-phenyl-1,3-dioxolan-4-yl) methyl]amino}butyl) N',N'-dihydroxyethanediimidamide
Titel:
The synthesis, characterization and spectral studies of Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) complexes with N,N-bis(2-{[(2-methyl-2-phenyl-1,3-dioxolan-4-yl) methyl]amino}butyl) N',N'-dihydroxyethanediimidamide
Auteur:
Canpolat, E. Kaya, M.
Verschenen in:
Journal of coordination chemistry
Paginering:
Jaargang 58 (2005) nr. 10 pagina's 875-882
Jaar:
2005-07-10
Inhoud:
CoII, NiII, CuII, ZnII and CdII complexes of N,N-bis(2-{[(2-methyl-2-phenyl-1,3-dioxolan-4-yl)methyl]amino}butyl)N',N'-dihydroxyethanediimidamide (LH2) were synthesized and characterized by elemental analyses, IR, 1H- and 13C-NMR spectra, electronic spectra, magnetic susceptibility measurements, conductivity measurements and thermogravimetric analyses (TGA). The CoII, NiII and CuII complexes of LH2 were synthesized with 1 : 2 metal ligand stoichiometry. ZnII and CdII complexes with LH2 have a metal ligand ratio of 1 : 1. The reaction of LH2 with CoII, NiII, CuII, ZnII and CdII chloride give complexes Ni(LH)2, Cu(LH)2, Zn(LH2)(Cl)2, Cd(LH2)(Cl)2, respectively.
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