Synthesis, crystal structure, and spectroscopic properties of CuL [H2L=2,3-dioxo-5,6:13,14-dichlorobenzo-7,12-diphenyl-1,4,8,11-tetra-azacyclo-pentadeca-7,11-diene] and [(LCu)Cu(phen)(EtOH)](ClO4)2 · EtOH · 0.25H2O: from mono- to dinuclear complex
Titel:
Synthesis, crystal structure, and spectroscopic properties of CuL [H2L=2,3-dioxo-5,6:13,14-dichlorobenzo-7,12-diphenyl-1,4,8,11-tetra-azacyclo-pentadeca-7,11-diene] and [(LCu)Cu(phen)(EtOH)](ClO4)2 · EtOH · 0.25H2O: from mono- to dinuclear complex
Auteur:
Zhang, Rui-Hong Wang, Qing-Lun Yang, Guang-Ming
Verschenen in:
Journal of coordination chemistry
Paginering:
Jaargang 59 (2006) nr. 10 pagina's 1183-1189
Jaar:
2006-07-10
Inhoud:
Based on the complex ligand CuL (H2L = 2,3-dioxo-5,6:13,14-dichlorobenzo-7,12-diphenyl-1,4,8,11-tetraazacyclo-pentadeca-7,11-diene) (1), a dinuclear complex [(LCu)Cu(phen)(EtOH)](ClO4)2 · EtOH · 0.25H2O (2) was prepared. The crystal structures of 1 and 2 have been determined. IR, electronic and EPR spectra are discussed.