|
| << vorige | volgende >> |
Tijdschrift beschrijving
Alle jaargangen van het bijbehorende tijdschrift
Alle afleveringen van het bijbehorende jaargang
Alle artikelen van de bijbehorende aflevering
Details van artikel 47 van 86 gevonden artikelen
| Titel: |
Synthesis and characterization of a nickel metavanadate complex: Ni(pz)(V2O6) (pz = pyrazine) |
| Auteur: |
Jiang, Ya-Qi Xu, Zhi-Hui Xie, Zhao-Xiong |
| Verschenen in: |
Journal of coordination chemistry |
| Paginering: | Jaargang 61 (2008) nr. 10 pagina's 1575-1581 |
| Jaar: |
2008 |
| Inhoud: |
A nickel metavanadate complex Ni(pz)(V2O6) (pz = pyrazine) (1) was hydrothermally synthesized and characterized by elemental analysis, IR spectroscopy and thermal analysis. The complex was also investigated by single crystal X-ray diffraction analysis. The three-dimensional extended structure in the crystal is constructed by corner sharing {VO3}n chains running along the b axis and two types of {Ni(pz)}n chains oriented in [0 1 1] and [0 1 -1] directions, respectively. Ni is coordinated by two N atoms from two pyrazines and four O atoms from three metavanadates in a distorted octahedral geometry. The variable-temperature magnetic susceptibility of 1 was measured. The magnetic coupling parameter indicates an antiferromagnetic interaction within the {Ni(pz)}n chain. |
| Uitgever: |
Taylor & Francis |
| Bronbestand: |
Elektronische Wetenschappelijke Tijdschriften |
Details van artikel 47 van 86 gevonden artikelen
| << vorige | volgende >> |