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Details for article 40 of 86 found articles
| Title: |
Syntheses and crystal structures of transition metal complexes of 1,1'-bisacetylacetoferrocene |
| Author: |
Yan, Chao-Guo Zhu, Mei-Jun Sun, Jing Liu, Wei-Long Shi, Yao-Cheng |
| Appeared in: |
Journal of coordination chemistry |
| Paging: | Volume 60 (2007) nr. 10 pages 1083-1091 |
| Year: |
2007 |
| Contents: |
Bimetallic complexes 3a-e of 1,1'-bisacetylacetoferrocene (2) were prepared by reactions of transition metal acetates M(OAc)2 (M = Co2+, Mn2+, Cu2+, Ni2+, Zn2+) with the 2 in refluxing methanol. The X-ray structures of the cobalt and manganese complexes were determined showing very similar centrosymmetric macrocyclic dimeric frameworks constituted by linkage of two Co2+ or Mn2+ ions and two 1,1'-diacetoacetylferrocene units with two additional methanols as bridges dividing this macrocyclic framework into two small cyclic subunits. The UV-Vis spectra and electronic properties were also studied. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 40 of 86 found articles
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