A new lithium complex with (iPr2C6H3)2-dad (N, N'-bis (iPr2C6H3)-1,4-diaza-1,3-butadiene) has been synthesized. The crystal structure of {Li3[iPr2C6H3)2-dad]2}{Li(THF)4}·0.5 Hexane [triclinic, Pī, a = 1.3154(2), b = 1.6720(2)nm, c = 1.8283(3) nm, α = 83.762(4), β = 70.152(2), γ = 68.267(2)°, V = 3.5127(8)nm3, Dc = 1.05g cm-3, Z = 2] is described.