A linear chain polymer {Ag2[S2P(OC2H5)2]2(bix)}n with multiple emission and red luminescence
Titel:
A linear chain polymer {Ag2[S2P(OC2H5)2]2(bix)}n with multiple emission and red luminescence
Auteur:
Li, Tao Li, Zhi-Hua Du, Shao-Wu
Verschenen in:
Journal of coordination chemistry
Paginering:
Jaargang 61 (2008) nr. 10 pagina's 1599-1605
Jaar:
2008
Inhoud:
The linear chain {Ag2[S2P(OC2H5)2]2(bix)}n 1 was obtained from reaction of Ag[S2P(OC2H5)2] with bix (bix = 1,4-bis(imidazole-l-ylmethyl)benzene). Compound 1 consists of a dinuclear module with intramolecular Ag ··· Ag interactions (2.9842(5) Å). This interaction shows a profound influence on the observed multiple luminescence emissions for 1. Crystal data for 1 at 293(2) K: Space group P1, a = 9.7158(1), b = 9.8273(2), c = 10.0758(2) Å, α = 70.989(1), β = 89.308(1), γ = 63.868(1)°, V = 806.75(2) Å3, Z = 1, R1 = 0.0294.