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  Epitaxy and interfacial phase in thin films of lead scandium tantalate deposited by reactive sputtering on a platinum interlayer
 
 
Titel: Epitaxy and interfacial phase in thin films of lead scandium tantalate deposited by reactive sputtering on a platinum interlayer
Auteur: Meekison, C. D.
Baba-Kishi, K. Z.
Watton, R.
Todd, M. A.
Verschenen in: Integrated ferroelectrics
Paginering: Jaargang 9 (1995) nr. 4 pagina's 283-291
Jaar: 1995-08-01
Inhoud: Lead scandium tantalate (PST) films with a lead-rich composition were deposited at 500°C by RF sputtering on sapphire substrates coated with Pt and were investigated by cross-sectional transmission electron microscopy. The films consisted almost entirely of the perovskite phase. The grains of perovskite PST had a crystallographic orientation almost parallel to that of the underlying Pt. Some elongated voids were observed. The presence of an interfacial phase, with interplanar spacings consistent with a pyrochlore phase, was demonstrated by electron diffraction and dark-field imaging. The crystallographic orientation of this phase is also nearly parallel to that of the Pt. Energy-dispersive X-ray microanalysis showed that the interfacial phase is lead-deficient. The interfacial phase is irregular in thickness. A reduction in the Pb content of the film leads to a thicker interfacial layer. The implications for the mechanism of growth of PST on Pt and for improvement of the film quality are discussed.
Uitgever: Taylor & Francis
Bronbestand: Elektronische Wetenschappelijke Tijdschriften
 
 

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