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                                       Details for article 14 of 15 found articles
 
 
  Stone-Wales Rearrangement as the Double Olefin-Carbene 1,2-CC Bond Shift. Denied Role of Triplet Biradicals
 
 
Title: Stone-Wales Rearrangement as the Double Olefin-Carbene 1,2-CC Bond Shift. Denied Role of Triplet Biradicals
Author: O¯sawa, Eiji
Slanina, Zdenek
Honda, Kazuhiko
Zhao, Xiang
Appeared in: Fullerenes, nanotubes & carbon nanostructures
Paging: Volume 6 (1998) nr. 2 pages 259-270
Year: 1998-03-01
Contents: Stone-Wales rearrangement may be considered to consist of two contiguous steps of olefin-carbene 1,2-C-C bond shift. Computational study on this mechanism led to high activation energies comparable to the bond dissociation energies of C-C bonds in fullerenes and their precursors. the possibility of passing through triplet transition state is denied on computational grounds.
Publisher: Taylor & Francis
Source file: Elektronische Wetenschappelijke Tijdschriften
 
 

                             Details for article 14 of 15 found articles
 
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