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Details van artikel 3 van 124 gevonden artikelen
| Titel: |
Addition Reactions of Benzyne, Dienes, Dichlorocarbene, and Oxygen to C60 |
| Auteur: |
Nogami, Takashi Tsuda, Minoru Ishida, Takayuki Kurono, Sadamu Ohashi, Mamoru |
| Verschenen in: |
Fullerenes, nanotubes & carbon nanostructures |
| Paginering: | Jaargang 1 (1993) nr. 3 pagina's 275-285 |
| Jaar: |
1993-08-01 |
| Inhoud: |
Benzyne was found to add to C60 in good yield to give C60(C6H4)n (n=1-4). Typical Diels-Alder dienes were also found to add to C60 under thermally mild conditions. Adducts of C60 with 2,3-dimethylbutadiene, cyclopentadiene, hexa-chlorocyclopentadiene, 1,3-diphenylisobenzofuran, and anthracene were obtained. Further reactions of these products such as elimination and autooxidation reactions were investigated. Addition reaction of dichlorocarbene to C60 gave C61Cl2. Oxidation of C60 with m-chloroperbenzoic acid gave C60On(n=1, 2). All of the products were isolated by means of HPLC and characterized by mass spectroscopy. |
| Uitgever: |
Taylor & Francis |
| Bronbestand: |
Elektronische Wetenschappelijke Tijdschriften |
Details van artikel 3 van 124 gevonden artikelen
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