C60 Hexagonal Solvate Grown from n-Octane: Solid-State Studies
Titel:
C60 Hexagonal Solvate Grown from n-Octane: Solid-State Studies
Auteur:
Ceolin, R. Agafonov, V. Toscani, S. Gardette, M. F. Gonthier-Vassal, A. Szwarc, H.
Verschenen in:
Fullerenes, nanotubes & carbon nanostructures
Paginering:
Jaargang 5 (1997) nr. 3 pagina's 559-565
Jaar:
1997-04-01
Inhoud:
By slowly evaporating at room temperature solutions of C60 in n-octane, crystals of the hexagonal solvate C60 1 n-octane have been obtained (a = 10.10, c = 10.18 Å)., Although these crystals are formed with a negative volume excess of - 24 Å3 per formula-unit, their desolvation enthalpy, 60 J g-1 (50 kJ mol-1), is close to the sublimation enthalpy of pure n-octane.