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Details for article 26 of 29 found articles
| Title: |
Weak Forces in Thermodynamic Stereoselectivity of Dipeptide Complex Formation in Aqueous Solution |
| Author: |
Cucinotta, Vincenzo Purrello, Roberto Rizzarelli, Enrico |
| Appeared in: |
Comments on inorganic chemistry |
| Paging: | Volume 11 (1990) nr. 2-3 pages 85-112 |
| Year: |
1990-12-01 |
| Contents: |
The thermodynamic stereoselectivity of a wide series of dipeptide complexes with proton and copper (II) ions is examined. In particular, it is shown that non-covalent interactions are the driving forces of the chirality discrimination. Furthermore, the diagnostic character of ΔH° and ΔS° values is brought to light and compared with the spectroscopy approach for correlating the stereoselectivity with the structural properties of complexes. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 26 of 29 found articles
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