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Details for article 24 of 29 found articles
| Title: |
The Stabilization of Low Oxidation States in σ- Organo Transition Metal Chemistry by Coordinative Lithium Transition Metal Interaction |
| Author: |
Taube, Rudolf |
| Appeared in: |
Comments on inorganic chemistry |
| Paging: | Volume 3 (1984) nr. 2-3 pages 69-81 |
| Year: |
1984-02-01 |
| Contents: |
Starting from the well known connection between the accessibility of different oxidation states of the transition metals and the donor-acceptor characteristics of the ligands, synthesis and structural characterization of electron-rich phenyl transition metal complexes are reviewed. To explain the existence of these unusual compounds in accordance with Pauling's principle of electroneutrality, a coordinative interaction of lithium ions with the central transition metal atom has been suggested as a new principle of stabilization of low oxidation states in coordination chemistry. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 24 of 29 found articles
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