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  Soot Formation During Pyrolysis of Methane and Rich Methane/Oxygen Mixtures Behind Reflected Shock Waves
 
 
Titel: Soot Formation During Pyrolysis of Methane and Rich Methane/Oxygen Mixtures Behind Reflected Shock Waves
Auteur: Agafonov, G. L.
Borisov, A. A.
Smirnov, V. N.
Troshin, K. Ya.
Vlasov, P. A.
Warnatz, Jurgen
Verschenen in: Combustion science and technology
Paginering: Jaargang 180 (2008) nr. 10-11 pagina's 1876-1899
Jaar: 2008-10
Inhoud: The pyrolysis of CH4/Ar and rich CH4/O2/Ar mixtures behind reflected shock waves were studied both experimentally and theoretically. The experiments were carried out behind reflected shock waves. Simulations were performed within the framework of a detailed kinetic model involving more than 260 species and 2500 elementary steps. The measured and calculated time profiles of soot yield and soot particle temperatures for CH4/Ar and CH4/O2/Ar mixtures proved to be in good agreement. The proposed kinetic model can also describe the temperature and pressure dependences of the ignition delay time for stoichiometric CH4/O2 mixture at low pressures and for rich CH4/O2 mixtures at elevated pressures over a wide pressure range, as well as the promoting effect of C2H6 and C3H8 additives.
Uitgever: Taylor & Francis
Bronbestand: Elektronische Wetenschappelijke Tijdschriften
 
 

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