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| Titel: |
DESORPTION OF ETHYL ACETATE-WATER MIXTURE BY USING CROSS-LINKED POLY(VINYLALCOHOL) MEMBRANE AND COMPARISON OF RESULTS WITH PERVAPORATION |
| Auteur: |
Korkmaz, Sevinc Salt, Yavuz Hasanoglu, Ayca Ozkan, Semra Dincer, Salih |
| Verschenen in: |
Chemical engineering communications |
| Paginering: | Jaargang 195 (2008) nr. 6 pagina's 585-599 |
| Jaar: |
2008-06 |
| Inhoud: |
In this study using poly(vinylalcohol) (PVOH) membranes cross-linked with tartaric acid (Tac) desorption experiments were performed for selected concentrations of binary ethyl acetate (EtAc)-water mixture at temperatures of 30°, 40°, and 50°C to determine sorption of components. Sorption values measured were compared with those estimated by the Flory-Huggins approach. Additionally, desorption results were compared with pervaporation results of another study in terms of solution-diffusion theory, and the effect of thermodynamic interactions on selective transport of the binary mixture and membrane system was investigated. The results obtained show that selective transport of EtAc-water mixture was influenced by increasing temperature and water content in the feed. It is shown that preferential sorption is more effective for pervaporation selectivity than diffusion selectivity. |
| Uitgever: |
Taylor & Francis |
| Bronbestand: |
Elektronische Wetenschappelijke Tijdschriften |
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