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| Titel: |
THE MODIFIED PGR EQUATION OF STATE: ASYMMETRIC MIXTURE VLE REPRESENTATIONS AND PREDICTIONS |
| Auteur: |
Row, K. H. Park, J. K. Gasem, K. A. M. |
| Verschenen in: |
Chemical engineering communications |
| Paginering: | Jaargang 195 (2008) nr. 5 pagina's 492-510 |
| Jaar: |
2008-05 |
| Inhoud: |
A set of mixing rules was proposed for the modified Park-Gasem-Robinson (PGR) equation of state (EOS) to extend its predictions to mixtures. The phase behavior predictive capability of this segment-segment interaction model was evaluated for selected binary asymmetric mixtures involving ethane, carbon dioxide, and hydrogen in normal paraffins. The predicted bubble point pressures for the ethane + n-paraffin and carbon dioxide + n-paraffin binaries were compared to those of the Peng-Robinson (PR), simplified perturbed hard-chain theory (SPHCT), and original PGR equations. The a priori predictive capability of the modified PGR EOS is significantly better than that of the PR, SPHCT, and original PGR equations of state for ethane binaries with absolute-average percent deviation (%AAD) of 5%. However, this EOS produces comparable representations for ethane binaries (%AAD of 1.9%) and carbon dioxide binaries (%AAD of 2.0). For hydrogen binaries, the modified PGR EOS showed much better representations (%AAD of 1.7) than the original PGR equation and was comparable to the PR equation. |
| Uitgever: |
Taylor & Francis |
| Bronbestand: |
Elektronische Wetenschappelijke Tijdschriften |
Details van artikel 8 van 8 gevonden artikelen
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