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| Titel: |
Commercial Applications of Reactions Catalyzed by Soluble Complexes of Cobalt and Rhodium |
| Auteur: |
Parshall, G. W. |
| Verschenen in: |
Catalysis reviews |
| Paginering: | Jaargang 23 (1981) nr. 1-2 pagina's 107-124 |
| Jaar: |
1981 |
| Inhoud: |
The past quarter century has witnessed an enormous transformation in the use of soluble transition metal complexes as catalysts in the chemical process industries. Until the mid-1950s, industrial use of homogeneous catalysis was largely confined to reactions of acetylene [1]. As indicated in Fig. 1, a large family of acetylene-based reactions was used to produce polymer intermediates such as vinyl acetate, vinyl chloride, acrylonitrile, chloroprene, and 1,4-butanediol. The processes were simple but they were relatively expensive because they were based on an expensive raw material. The large energy content of the acetylene molecule (ΔF°=50.84 kcal/mol) made it both hazardous to handle and expensive even in times when energy was cheaper. |
| Uitgever: |
Taylor & Francis |
| Bronbestand: |
Elektronische Wetenschappelijke Tijdschriften |
Details van artikel 6 van 45 gevonden artikelen
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